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I am looking for the name of John's first wife who died before March 1907.
He was living in Poplar, East London in 1912.

Is this him with his second wife in the 1911 census? :-

1911 census transcription details for: 11 Appian Road Bow

National Archive Reference:
RG14PN1676 RG78PN58 RD22 SD1 ED26 SN210
Reg. District: Poplar
Sub District: Bow
Parish: Poplar Borough
Enum. District: 26

Address: 11 Appian Road Bow
County: London

Name Relation Condition/
Yrs married Sex Age Birth Year Occupation Where Born

REYNOLDS, John Head Married 4 years M 36 1875 Twine Maker London Stepney
REYNOLDS, Catherine Wife Married F 28 1883 London Stepney
REYNOLDS, Catherine Daughter F 3 1908 London Bow
REYNOLDS, Rose Daughter F 0 (9 MONTHS) 1911 London Bow
REYNOLDS, Charlotte Daughter F 12 1899 School London Bow
REYNOLDS, Walter Son M 7 1904 School London Bow
REYNOLDS, William Brother Single M 31 1880 Rope Maker London Stepney
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If so then this seems to be him in the 1901 census with first wife (a bit older than he says in 1911 but that could be because his second wife is younger):-

1901 census transcription details for: 16, Ranwell Street, Bow Or Stratford-Le-Bow

National Archive Reference:
RG number: RG13
Piece: 341
Folio: 134
Page: 7
Reg. District: Poplar
Sub District: Bow
Parish: Bow or Stratford-Le-Bow
Enum. District: 17
Ecclesiastical District: St Pauls
City/Municipal Borough:

Address: 16, Ranwell Street, Bow Or Stratford-Le-Bow
County: London

Name Relation Condition Sex Age Birth Year Occupation , Disability Where Born

REYNOLDS, John Head Married M 28 1873 Twine Spinner
Limehouse, London
REYNOLDS, Charlotte Wife Married F 24 1877
Bow, London
REYNOLDS, Charlotte Daughter Single F 2 1899
Bow, London
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This looks like his first wife's death:-

Name: REYNOLDS, Charlotte
Registration district: Poplar
County: London
Year of registration: 1903
Quarter of registration: Oct-Nov-Dec
Age at death: 27
Volume no: 1C
Page no: 310

It looks as if she may have died in childbirth as this is the birth of the son Walter who is on the 1911 census:-

Name: REYNOLDS, Walter
Registration district: Poplar
County: London
Year of registration: 1903
Quarter of registration: Oct-Nov-Dec
Mother's maiden name: Not available before 1911 Q3
Volume no: 1C
Page no: 526
----------
This looks like his first marriage:-

Name: REYNOLDS, John
Registration district: Poplar
County: London
Year of registration: 1897
Quarter of registration: Apr-May-Jun
Spouse's last name: Not available before 1912
Volume no: 1C
Page no: 1133

MarriageFinder: John Reynolds married one of the following people:

CLARK, Edith Clara
HIGGINS, Charlotte<<<<<<<<<<<<<<<<<<<<<<<<<<
HARTSHORN, William

Kath. x

Thank you for your help Rose

His 2 marriages?

London, England, Marriages and Banns, 1754-1921
about John Reynolds Name: John Reynolds
Estimated Birth Year: abt 1874
Age: 23
Spouse Name: Charlotte Higgins
Spouse Age: 21
Record Type: Marriage
Event Date: 2 May 1897
Parish: Victoria Park St Mark
Borough: Tower Hamlets
Father Name: John Reynolds
Spouse Father Name: Samuel Higgins
Register Type: Parish Register


London, England, Marriages and Banns, 1754-1921
about John Reynolds Name: John Reynolds
Estimated Birth Year: abt 1876
Age: 31
Spouse Name: Catherine Perkins
Spouse Age: 24
Record Type: Marriage
Event Date: 31 Mar 1907
Parish: Victoria Park St Mark
Borough: Tower Hamlets
Father Name: John Reynolds
Spouse Father Name: Frederick Perkins
Register Type: Parish Register

He's a widower.